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Emergent property of high hardness for C-rich ruthenium carbides: partial covalent Ru–Ru bonds.
- Source :
- Physical Chemistry Chemical Physics (PCCP); 3/7/2018, Vol. 20 Issue 9, p6108-6115, 8p
- Publication Year :
- 2018
-
Abstract
- Hard materials are being investigated all the time by combining transition metals with light elements. Combining a structure search with first-principles functional calculations, we first discovered three stable stoichiometric C-rich ruthenium carbides in view of three synthesis routes, namely, the ambient phases of Ru<subscript>2</subscript>C<subscript>3</subscript> and RuC, and two high pressure phases of RuC<subscript>4</subscript>. There is a phase transition of RuC<subscript>4</subscript> from the P3̅m1 structure to the R3̅m structure above 98 GPa. The calculations of elastic constants and phonon dispersions show their mechanical and dynamical stability. The large elastic modulus, high Debye temperature and the estimated hardness values suggest that these hard ruthenium carbides have good mechanical properties. The analyses of electronic structure and chemical bonding indicate that chemical bonding, not carbon content, is the key factor for the hardness in these metallic C-rich ruthenium carbides. The partial covalent Ru–C bonds and strong covalent C–C bonds are responsible for the high hardness. Moreover, the emergence of partial covalent Ru–Ru bonds can enhance the hardness of RuC, while the ionic Ru–Ru bonds can weaken the hardness of Ru<subscript>2</subscript>C<subscript>3</subscript>. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14639076
- Volume :
- 20
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Physical Chemistry Chemical Physics (PCCP)
- Publication Type :
- Academic Journal
- Accession number :
- 128244678
- Full Text :
- https://doi.org/10.1039/c7cp07835h