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Non-covalent tetrel bonding interactions in hemidirectional lead(ii) complexes with nickel(ii)-salen type metalloligands.
- Source :
- New Journal of Chemistry; 4/21/2018, Vol. 42 Issue 8, p6062-6076, 15p
- Publication Year :
- 2018
-
Abstract
- Four hetero-dinuclear nickel(ii)/lead(ii) complexes have been synthesized and characterized. Their structures have been confirmed by single crystal X-ray diffraction studies. In each complex, nickel(ii) is placed in the inner N<subscript>2</subscript>O<subscript>2</subscript> compartment and lead(ii) in the outer O<subscript>2</subscript>O<subscript>2</subscript>′ compartment of the respective Schiff base. In complexes 1, 3 and 4, lead(ii) centres are hemidirectionally coordinated, and thus are well suited for establishing tetrel bonding interactions which have been investigated thoroughly by means of DFT calculations. [ABSTRACT FROM AUTHOR]
- Subjects :
- METAL complexes
LEAD compounds
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 42
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 129100984
- Full Text :
- https://doi.org/10.1039/c7nj05148d