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A Stable Metal–Organic Framework Featuring a Local Buffer Environment for Carbon Dioxide Fixation.
- Source :
- Angewandte Chemie International Edition; 4/16/2018, Vol. 57 Issue 17, p4657-4662, 6p
- Publication Year :
- 2018
-
Abstract
- Abstract: A majority of metal–organic frameworks (MOFs) fail to preserve their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous solutions, therefore limiting their practical applications in many areas. The strategy demonstrated herein is the design and synthesis of an organic ligand that behaves as a buffer to drastically boost the aqueous stability of a porous MOF (JUC‐1000), which maintains its structural integrity at low and high pH values. The local buffer environment resulting from the weak acid–base pairs of the custom‐designed organic ligand also greatly facilitates the performance of JUC‐1000 in the chemical fixation of carbon dioxide under ambient conditions, outperforming a series of benchmark catalysts. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 57
- Issue :
- 17
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 129103086
- Full Text :
- https://doi.org/10.1002/anie.201801122