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Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer.
- Source :
- Chemical Communications; 5/18/2018, Vol. 54 Issue 40, p5134-5137, 4p
- Publication Year :
- 2018
-
Abstract
- Hollow and microporous organic network bearing alkynone moieties was prepared via carbonylative Sonogashira coupling. The carbonyl groups in the network showed unusual chemical reactivities, compared with those of a model alkynone compound. The observed differences between the reactivities of alkynones in the molecule and in the network were analyzed based on the “network effect”. [ABSTRACT FROM AUTHOR]
- Subjects :
- CARBONYL group
POLYMERS
CHEMICAL reactions
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 40
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 129627360
- Full Text :
- https://doi.org/10.1039/c8cc02788a