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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network.
- Source :
- Chemical Communications; 6/28/2018, Vol. 54 Issue 51, p7042-7045, 4p
- Publication Year :
- 2018
-
Abstract
- A nonporous square lattice (sql) coordination network [Co(bipy)<subscript>2</subscript>(NCS)<subscript>2</subscript>]<subscript>n</subscript> (sql-1-Co-NCS) exhibits recyclable switching induced by CO<subscript>2</subscript>. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage. [ABSTRACT FROM AUTHOR]
- Subjects :
- ATMOSPHERIC temperature
HYSTERESIS
GAS storage
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 51
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 130279365
- Full Text :
- https://doi.org/10.1039/c8cc03838d