Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States.

Abstract: Deep convective transport of gaseous precursors to ozone (O₃) and aerosols to the upper troposphere is affected by liquid phase and mixed‐phase scavenging, entrainment of free tropospheric air and aqueous chemistry. The contributions of these processes are examined using aircraft measurements obtained in storm inflow and outflow during the 2012 Deep Convective Clouds and Chemistry (DC3) experiment combined with high‐resolution (dx≤3 km) WRF‐Chem simulations of a severe storm, an air mass storm, and a mesoscale convective system (MCS). The simulation results for the MCS suggest that formaldehyde (CH₂O) is not retained in ice when cloud water freezes, in agreement with previous studies of the severe storm. By analyzing WRF‐Chem trajectories, the effects of scavenging, entrainment, and aqueous chemistry on outflow mixing ratios of CH₂O, methyl hydroperoxide (CH₃OOH), and hydrogen peroxide (H₂O₂) are quantified. Liquid phase microphysical scavenging was the dominant process reducing CH₂O and H₂O₂ outflow mixing ratios in all three storms. Aqueous chemistry did not significantly affect outflow mixing ratios of all three species. In the severe storm and MCS, the higher than expected reductions in CH₃OOH mixing ratios in the storm cores were primarily due to entrainment of low‐background CH₃OOH. In the air mass storm, lower CH₃OOH and H₂O₂ scavenging efficiencies (SEs) than in the MCS were partly due to entrainment of higher background CH₃OOH and H₂O₂. Overestimated rain and hail production in WRF‐Chem reduces the confidence in ice retention fraction values determined for the peroxides and CH₂O. [ABSTRACT FROM AUTHOR]