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Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage.
- Source :
- Chemical Communications; 9/4/2018, Vol. 54 Issue 68, p9422-9425, 4p
- Publication Year :
- 2018
-
Abstract
- A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO<subscript>2</subscript><superscript>2+</superscript>) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediates the transformation of cage-1 to cage-2via the activation of molecular oxygen. [ABSTRACT FROM AUTHOR]
- Subjects :
- URANYL compounds synthesis
PHOTOCHEMISTRY
CHEMICAL reactions
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 68
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 131347138
- Full Text :
- https://doi.org/10.1039/c8cc05160g