Impact of the Temperature in the Evaluation of Battery Performances During Long-Term Cycling—Characterisation and Modelling.

Featured Application: In the long term, results presented with this paper suggest to carry out in a systematic manner, the evaluation of batteries performances at the cycling temperature. According to this, in real applications as in automotive, it can be recommended to use the track of the temperature within the battery pack (e.g., mean) recorded by the battery management system, to define the temperature at which battery cells performances should be evaluated. In addition, room temperature can be used if needed for the comparison of battery cells performances, of same type that are though not operating at the same temperature. This paper presents the results regarding the thermal characterisation and modelling of high energy lithium-ion battery cells at both room (25 °C) and cycling (35 °C) temperatures. In this work two types of Nickel Manganese Cobalt (NMC) batteries are studied: a fresh (or uncycled) and an aged (or cycled) battery cells. The ageing of the studied NMC battery cells is achieved by means of accelerated ageing tests (i.e., repetition of numerous charge and discharge cycles) at 35 °C cycling temperature. Temperature at the surface of the battery cells is characterised, with a set of three discharge current rates 0.3C (i.e., 6 A), 1C (i.e., 20 A) and 2C (i.e., 40 A), and the evolutions at three different locations on the surface of the battery cells namely, at the top, in the center and at the bottom regions are measured. In addition, temperature and ageing dependent electrochemical-thermal modelling of the uncycled and cycled battery cells is also successfully accomplished in case of both room and cycling temperatures. Numerical simulations were carried out in case of high 2C constant current rate, and the assessment of the modelling accuracy by comparison of the predicted battery cells voltage and temperature with respect to the experimental data is further presented. With this paper, thermal performances of battery cells prior and after long-term cycling are evaluated at the cycling temperature, next to the ambient temperature. Hence, thermal characterisation and modelling results are more closely reflecting that encountered by the battery cells in real cycling conditions, so that their performances are believed in this way to be more objectively evaluated. [ABSTRACT FROM AUTHOR]