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Heterostructure CoS/NC@MoS2 Hollow Spheres for High‐Performance Hydrogen Evolution Reactions and Lithium‐ION Batteries.
- Source :
- ChemElectroChem; 12/10/2018, Vol. 5 Issue 24, p3953-3960, 8p
- Publication Year :
- 2018
-
Abstract
- Uniquely structured CoS/N‐doped carbon@MoS2 (denoted as CoS/NC@MoS2) hollow spheres were successfully synthesized by using a well‐designed N‐rich Co‐metal organic framework (ZIF‐67) precursor and template. Owing to the good mechanical stability and conductivity of carbon hollow spheres, N‐doped carbon, and Co−Mo bonds, the as‐prepared CoS/NC@MoS2 composites exhibit outstanding electrochemical performance both in electrocatalytic and energy storage applications. An overpotential of 77 mV at 10 mA cm−2, and a Tafel slope of 67 mV dec−1 could be obtained in acid environment for the hydrogen evolution reaction. As an anode material for lithium‐ion batteries, the as‐prepared composites exhibit good cycling stability with a high reversible specific capacity of 802.4 mA h g−1 at a current density of 1 A g−1 after 400 cycles and good rate capability. Time to evolve: CoS/NC@MoS2 hollow spheres show outstanding electrocatalytic hydrogen evolution properties and good cycling stability as the anode for lithium‐ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21960216
- Volume :
- 5
- Issue :
- 24
- Database :
- Complementary Index
- Journal :
- ChemElectroChem
- Publication Type :
- Academic Journal
- Accession number :
- 133481643
- Full Text :
- https://doi.org/10.1002/celc.201801166