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Morphology, Thermal, Mechanical Properties and Rheological Behavior of Biodegradable Poly(butylene succinate)/poly(lactic acid) In-Situ Submicrofibrillar Composites.
- Source :
- Materials (1996-1944); Dec2018, Vol. 11 Issue 12, p2422, 1p, 3 Diagrams, 2 Charts, 7 Graphs
- Publication Year :
- 2018
-
Abstract
- In this study, biodegradable poly(butylene succinate)/poly(lactic acid) (PBS/PLA) in-situ submicrofibrillar composites with various PLA content were successfully produced by a triple-screw extruder followed by a hot stretching−cold drawing−compression molding process. This study aimed to investigate the effects of dispersed PLA submicro-fibrils on the thermal, mechanical and rheological properties of PBS/PLA composites. Morphological observations demonstrated that the PLA phases are fibrillated to submicro-fibrils in the PBS/PLA composites, and all the PLA submicro-fibrils produced seem to have a uniform diameter of about 200nm. As rheological measurements revealed, at low frequencies, the storage modulus (G') of PBS/PLA composites has been increased by more than four orders of magnitude with the inclusion of high concentrations (15 wt % and 20 wt %) of PLA submicro-fibrils, which indicates a significant improvement in the elastic responses of PBS melt. Dynamic Mechanical Analysis (DMA) results showed that the glass transition temperature (T<subscript>g</subscript>) of PBS phase slightly shifted to the higher temperature after the inclusion of PLA. DSC experiments proved that fiber morphology of PLA has obvious heterogeneous nucleation effect on the crystallization of PBS. The tensile properties of the PBS/PLA in-situ submicrofibrillar composites are also improved compared to neat PBS. [ABSTRACT FROM AUTHOR]
- Subjects :
- BIODEGRADABLE materials
POLYBUTENES
POLYLACTIC acid
NUCLEATION
CRYSTALLIZATION
Subjects
Details
- Language :
- English
- ISSN :
- 19961944
- Volume :
- 11
- Issue :
- 12
- Database :
- Complementary Index
- Journal :
- Materials (1996-1944)
- Publication Type :
- Academic Journal
- Accession number :
- 133722594
- Full Text :
- https://doi.org/10.3390/ma11122422