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Supramolecular aggregation of a redox-active copper-naphthalenediimide network with intrinsic electron conduction.
- Source :
- Chemical Communications; 2/7/2019, Vol. 55 Issue 11, p1643-1646, 4p
- Publication Year :
- 2019
-
Abstract
- A sextuple ordered interpenetrated copper-naphthalenediimide network has been constructed by combining the features of porous metal–organic frameworks and π-conjugated supramolecular aggregation. The material exhibits intrinsic semiconductive features with narrow bandgap energy (1.2 eV) and outstanding electron transport. Theoretical calculations combined with experiments indicate that the high electron conduction may originate from π–d coupling and J-aggregation. [ABSTRACT FROM AUTHOR]
- Subjects :
- SUPRAMOLECULAR chemistry
CONDUCTION electrons
REDOX polymers
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 134404476
- Full Text :
- https://doi.org/10.1039/c8cc10269d