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Redox chemistry of an anionic dithiolene radical.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 3/21/2019, Vol. 48 Issue 11, p3543-3546, 4p
- Publication Year :
- 2019
-
Abstract
- The redox chemistry of the first stable anionic dithiolene radical 1Ṗ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1Ṗ by Cp<subscript>2</subscript>Co or KC<subscript>8</subscript> affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of 1Ṗ by Ph<subscript>3</subscript>C<superscript>+</superscript>BF<subscript>4</subscript><superscript>−</superscript> (or O<subscript>2</subscript>) conveniently gives 4, the neutral dithiolene dimer. [ABSTRACT FROM AUTHOR]
- Subjects :
- CHEMISTRY
OXIDATION-reduction reaction
CYCLIC voltammetry
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 48
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 135264003
- Full Text :
- https://doi.org/10.1039/c8dt04989k