Back to Search
Start Over
Photoluminescence Characteristics of Sn2+ and Ce3+-Doped Cs2SnCl6 Double-Perovskite Crystals.
- Source :
- Materials (1996-1944); May2019, Vol. 12 Issue 9, p1501, 1p, 1 Diagram, 1 Chart, 9 Graphs
- Publication Year :
- 2019
-
Abstract
- In recent years, all-inorganic lead-halide perovskites have received extensive attention due to their many advantages, but their poor stability and high toxicity are two major problems. In this paper, a low toxicity and stable Cs<subscript>2</subscript>SnCl<subscript>6</subscript> double perovskite crystals were prepared by aqueous phase precipitation method using SnCl<subscript>2</subscript> as precursor. By the XRD, ICP-AES, XPS, photoluminescence and absorption spectra, the fluorescence decay curve, the structure and photoluminescence characteristics of Ce<superscript>3+</superscript>-doped and undoped samples have been investigated in detail. The results show that the photoluminescence originates from defects. [ S n S n 4 + 2 + +V<subscript>Cl</subscript>] defect complex in the crystal is formed by Sn<superscript>2+</superscript> substituting Sn<superscript>4+</superscript>. The number of defects formed by Sn<superscript>2+</superscript> in the crystal decreases with Ce<superscript>3+</superscript> content increases. Within a certain number of defects, the crystal luminescence is enhanced with the number of [ S n S n 4 + 2 + +V<subscript>Cl</subscript>] decreased. When Ce<superscript>3+</superscript> is incorporated into the crystals, the defects of [ C e 3 + S n 4 + +V<subscript>Cl</subscript>] and [ S n S n 4 + 2 + +V<subscript>Cl</subscript>] were formed and the crystal show the strongest emission. This provides a route to enhance the photoluminescence of Cs<subscript>2</subscript>SnCl<subscript>6</subscript> double perovskite crystals. [ABSTRACT FROM AUTHOR]
- Subjects :
- LEAD
HALIDES
PEROVSKITE
METEOROLOGICAL precipitation
PHOTOLUMINESCENCE
Subjects
Details
- Language :
- English
- ISSN :
- 19961944
- Volume :
- 12
- Issue :
- 9
- Database :
- Complementary Index
- Journal :
- Materials (1996-1944)
- Publication Type :
- Academic Journal
- Accession number :
- 136586348
- Full Text :
- https://doi.org/10.3390/ma12091501