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Activation and Spillover of Hydrogen on Sub‐1 nm Palladium Nanoclusters Confined within Sodalite Zeolite for the Semi‐Hydrogenation of Alkynes.
- Source :
- Angewandte Chemie International Edition; 6/3/2019, Vol. 58 Issue 23, p7668-7672, 5p
- Publication Year :
- 2019
-
Abstract
- The search for efficient nontoxic catalysts able to perform industrial hydrogenations is a topic of interest, with relevance to many catalytic processes. Herein, we describe a mechanistic phenomenon for the activation and spillover of hydrogen for remarkable selectivity in the semi‐hydrogenation of acetylene over sub‐1 nm Pd nanoclusters confined within sodalite (SOD) zeolite (Pd@SOD). Specifically, hydrogen is dissociated on the Pd nanoclusters to form hydrogen species (i.e., hydrogen atoms and hydroxyl groups) that spill over the SOD surfaces. The design and utilization of the small‐pore zeolite SOD (six‐membered rings with 0.28×0.28 nm channels) is crucial as it only allows H2 diffusion into the channels to reach the encapsulated Pd nanoclusters and thus avoids over‐hydrogenation to form ethane. Pd@SOD exhibits an ethylene selectivity of over 94.5 %, while that of conventional Pd/SOD is approximately 21.5 %. [ABSTRACT FROM AUTHOR]
- Subjects :
- SODALITE
HYDROXYL group
ALKYNES
HYDROGEN atom
PALLADIUM
HYDROGEN
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 58
- Issue :
- 23
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 136643031
- Full Text :
- https://doi.org/10.1002/anie.201903827