Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О Glass as a Precursor for the Synthesis of Crystalline Аl2(SO4)3 ⋅ 8(CH3)2SO

Authors :: Kirilenko, I. A.
Panasyuk, G. P.
Azarova, L. A.
Demina, L. I.
Kozerozhets, I. V.
Vasil'ev, M. G.
Source :: Russian Journal of Inorganic Chemistry; Jul2019, Vol. 64 Issue 7, p941-945, 5p
Publication Year :: 2019
Abstract: The new compound Аl<subscript>2</subscript>(SO<subscript>4</subscript>)<subscript>3</subscript> ⋅ 8(CH<subscript>3</subscript>)<subscript>2</subscript>SO, which cannot be prepared by direct synthesis, has been synthesized from an Аl<subscript>2</subscript>(SO<subscript>4</subscript>)<subscript>3</subscript> ⋅ 8(CH<subscript>3</subscript>)<subscript>2</subscript>SO ⋅ 3Н<subscript>2</subscript>О glass. The compound has been identified by X-ray diffraction. Based on IR spectra, it has been concluded that the Al<superscript>3+</superscript> ion has mixed coordination to dimethylsulfoxide (DMSO) molecules, and the ligands are linked to each other through the S and O atoms. [ABSTRACT FROM AUTHOR]

Full Text Access

Tools