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Phosphine‐Catalyzed [3+2] Cycloaddition and Vinylation of Indole‐Derived α,α‐Dicyanoolefins with γ‐Substituted Allenoates.
- Source :
- Asian Journal of Organic Chemistry; Oct2019, Vol. 8 Issue 10, p1893-1902, 10p
- Publication Year :
- 2019
-
Abstract
- A phosphine‐catalyzed [3+2] cycloaddition of γ‐substituted allenoates with α,α‐dicyanoolefins has been established, affording indole‐incorporated highly functionalized cyclopentenes. In addition, the vinylation of indole‐derived α,α‐dicyanoolefins has also been realized under the same reaction conditions by switching to indole‐derived α,α‐dicyanoolefins without protective group at N‐1 position. [ABSTRACT FROM AUTHOR]
- Subjects :
- VINYLATION
RING formation (Chemistry)
INDOLE
PHOSPHINE
Subjects
Details
- Language :
- English
- ISSN :
- 21935807
- Volume :
- 8
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Asian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 139054053
- Full Text :
- https://doi.org/10.1002/ajoc.201900393