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Bi(OAc)3/chiral phosphoric acid catalyzed enantioselective allylation of isatins.
- Source :
- Chemical Communications; 1/7/2020, Vol. 56 Issue 2, p261-264, 4p
- Publication Year :
- 2020
-
Abstract
- Herein, we disclosed an efficient protocol for the construction of chiral 3-allyl-3-hydroxyoxindoles via the enantioselective allylation reaction of isatins and allylboronates catalyzed by a simple binary acid Bi(OAc)<subscript>3</subscript>/CPA system under mild conditions. The synthetic utility of this strategy has been demonstrated through the formal synthesis of ent-CPC-1. [ABSTRACT FROM AUTHOR]
- Subjects :
- ALLYLATION
PHOSPHORIC acid
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 140474480
- Full Text :
- https://doi.org/10.1039/c9cc07944k