Preparation of monosultap‐polyurethane microcapsules in an inverse emulsion through interfacial polymerization.

In this study, we prepared monosultap microcapsules in an inverse emulsion through interfacial polymerization for the first time. The microcapsules are spherical pellets with intact and smooth shell and have a narrow particle size distribution with an average size of about 2.35 μm. More importantly, our microcapsules have excellent thermal stability with a starting decomposition temperature of 233.1 °C, high encapsulation efficiency of 81.9% as well as long‐term slow release of monosultap under different conditions. In addition, the shell of the microcapsules can degrade completely in the natural condition, avoiding the pollution to the environment. It can be believed that our microcapsules will show good service performance if employed in agricultural industry. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020, 137, 48594. [ABSTRACT FROM AUTHOR]