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M4LiBe4P7O24 and M4Li(Li3P)P7O24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework.
- Source :
- Chemical Communications; 8/7/2020, Vol. 56 Issue 61, p8639-8642, 4p
- Publication Year :
- 2020
-
Abstract
- New paracelsian-like beryllophosphates M<subscript>4</subscript>LiBe<subscript>4</subscript>P<subscript>7</subscript>O<subscript>24</subscript> and their tetrahedra-substituted phases M<subscript>4</subscript>Li(Li<subscript>3</subscript>P)P<subscript>7</subscript>O<subscript>24</subscript> (MLiP<subscript>2</subscript>O<subscript>6</subscript>, M = Cs, Rb) were designed and synthesized. Interestingly, two types of phases undergo a structural transformation, resulting from the radius and valence charge number of tetrahedral cations. Four crystals demonstrate potential deep-UV NLO properties such as short absorption edges (<190 nm) and phase-matching SHG response. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 56
- Issue :
- 61
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 144871919
- Full Text :
- https://doi.org/10.1039/d0cc03159c