Chemical Characteristics and Brown Carbon Chromophores of Atmospheric Organic Aerosols Over the Yangtze River Channel: A Cruise Campaign.

Organic aerosols (OAs) have important influences on the climatic implications and health effects of atmospheric aerosols. Among the complex OA constituents, brown carbon (BrC) accounts for a substantial mass fraction and is of special interest because of its light‐absorbing properties. In this study, the chemical composition of atmospheric OAs over the middle‐lower Yangtze River (MLYR) channel, as well as the BrC, was investigated during a ship cruise campaign in winter 2015. In total, more than 1,000 molecular formulas were determined using a combination of ultra‐high performance liquid chromatography (UHPLC), a diode array detector (DAD), and Orbitrap high‐resolution mass spectrometry (HRMS). Large numbers and enhanced signal abundances for known tracers as well as monocyclic and polycyclic aromatics indicate that biomass burning and fossil combustion are important sources of OAs over the MLYR channel. In addition, 13 chromophores with strong light absorption, mostly representing established biomass burning tracers, were unambiguously determined by UHPLC/DAD/HRMS and contributed to 35–37% of the total light absorption of OAs at 290 nm and 58–70% at 350 nm. Sixty‐three previously identified biomass burning chromophores were also positively identified in the mass spectrometric analysis here but embedded in the humped signal during the spectroscopic analysis. These BrC chromophores exhibit high degrees of unsaturation, suggesting that these compounds are aromatic, nitro‐aromatic, and polycyclic aromatic type of species. Our results highlight the significant influence of biomass burning and fossil combustion on atmospheric OAs over the MLYR channel in the winter, strongly enhancing light‐absorbing properties and decreasing air quality. Key Points: More than 1,000 atmospheric particulate organics including 76 BrC chromophores were determined over the Yangtze River channelBrown carbon chromophores exhibit high degrees of unsaturation, suggesting that these compounds are aromatics, nitro‐aromatics, or polycyclic aromaticsBiomass burning tracers contribute significantly to the total light absorption of organic aerosols [ABSTRACT FROM AUTHOR]