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H2 photochemistry in interstellar ices:The formation of HCO in UV irradiated CO:H2 ice mixtures.

Authors :
Chuang, K.-J.
Fedoseev, G.
Qasim, D.
Ioppolo, S.
van Dishoeck, E. F.
Jäger, C.
Henning, T.
Linnartz, H.
Salama, Farid
Linnartz, Harold
Source :
Proceedings of the International Astronomical Union; Apr2019, Vol. 15 Issue S350, p404-405, 2p
Publication Year :
2019

Abstract

The role of H<subscript>2</subscript> in forming interstellar complex organics is still not clear due to the high activation energies required for "non-energetic" association reactions. In this work, we investigated the potential contribution of H<subscript>2</subscript> to the hydrogenated species (H<subscript>n</subscript>NCO) formation on dust grains when the "energetic" processing is involved. The goal is to test whether an additional hydrogenation pathway is possible upon UV irradiation of a CO:H<subscript>2</subscript> ice mixture. It is proposed that the electronically excited carbon monoxide (CO*) induced by UV-photons can react with a ground-state H<subscript>2</subscript> to form HCO, ultimately enhancing the production of COMs in ice mantle. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
17439213
Volume :
15
Issue :
S350
Database :
Complementary Index
Journal :
Proceedings of the International Astronomical Union
Publication Type :
Academic Journal
Accession number :
146393536
Full Text :
https://doi.org/10.1017/S1743921319009670