Back to Search
Start Over
Dually Decorated Na3V2(PO4)2F3 by Carbon and 3D Graphene as Cathode Material for Sodium‐Ion Batteries with High Energy and Power Densities.
- Source :
- ChemElectroChem; 10/1/2020, Vol. 7 Issue 19, p3975-3983, 9p
- Publication Year :
- 2020
-
Abstract
- The dually decorated Na3V2(PO4)2F3 by in‐situ formed carbon and three‐dimensional graphene (NVPF/C@3DG) is prepared via two hydrothermal steps and a high‐temperature calcination. Benefiting from the high electronic conductivity of carbon and 3DG, high surface area and the resulted high diffusion coefficients of Na+, NVPF/C@3DG displays superior electrochemical performance to the control NVPF/C. Between 2.5 and 4.5 V (vs. Na+/Na), NVPF/C@3DG presents the initial discharge capacity of 123.6 mAh g−1 at 0.2 C (25.6 mA g−1) and capacity retention of 92.1 % after 60 cycles, while NVPF/C shows initial discharge capacity of 119 mAh g−1 and capacity retention of 84.1 % under the identical test conditions. Even at 15 C, the initial discharge capacity and capacity retention after 1000 cycles of NVPF/C@3DG are as high as 91.2 mAh g−1 and 82.9 %, respectively, much better than the initial discharge capacity of 71.2 mAh g−1 and the corresponding capacity retention of 76.4 % for NVPF/C, respectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21960216
- Volume :
- 7
- Issue :
- 19
- Database :
- Complementary Index
- Journal :
- ChemElectroChem
- Publication Type :
- Academic Journal
- Accession number :
- 146470967
- Full Text :
- https://doi.org/10.1002/celc.202000881