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The Solid State Structure of [TMEDAH2][B5O6(OH)4]2.

Authors :
Begum, Farzana
Twamley, Brendan
Baker, Robert J.
Source :
Journal of Chemical Crystallography; Sep2020, Vol. 50 Issue 3, p171-175, 5p
Publication Year :
2020

Abstract

The solid state structure of the pentaborate anion templated by a doubly protonated TMEDA cation is reported. The structure is typical of this family of ligands, featuring extensive hydrogen bonding. Spectroscopic characterisation is also reported. The structure of [TMEDAH<subscript>2</subscript>][B<subscript>5</subscript>O<subscript>6</subscript>(OH)<subscript>4</subscript>]<subscript>2</subscript> is reported and hydrogen bonding gives a 'brickwall' type structure. This is a blue emitter in solution. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
HYDROGEN bonding

Details

Language :
English
ISSN :
10741542
Volume :
50
Issue :
3
Database :
Complementary Index
Journal :
Journal of Chemical Crystallography
Publication Type :
Academic Journal
Accession number :
147249756
Full Text :
https://doi.org/10.1007/s10870-019-00775-8