The Effect of the Martian 2018 Global Dust Storm on HDO as Predicted by a Mars Global Climate Model.

The deuterium to hydrogen (D/H) ratio is commonly used to investigate the history of water on Mars, yet the mechanisms controlling present‐day HDO behavior are poorly understood. Significant variations of the D/H ratio were first predicted on the basis of a 3D global climate model, which were later confirmed by ground‐based observations. This behavior, consisting of lower HDO/H2O ratios in the colder regions of Mars, is related to the isotopic fractionation occurring at condensation. We leverage this previous effort and present an updated implementation, using the modern version of the model, that remains in agreement with the older version. We explore the impact of the global dust storm (GDS) that occurred during Martian year 34 (MY34) on HDO. Our simulations indicate that HDO is on average 40% more abundant at 100 km during the MY34 GDS year than during a regular year, with likely large consequences for the escape flux of water that year. Plain Language Summary: HDO, the semi‐heavy isotope of water, when compared to water, is a good indicator of how much water has been escaping from the atmosphere of Mars over the ages. Ultimately, it can be used to estimate the past reservoir of water available on Mars in its early youth. Because HDO has a slightly higher molecular mass compared to H2O, condensation induces an enrichment of HDO in the ice phase compared with the vapor phase. This subsequently causes spatial and temporal variations of the deuterium to hydrogen ratio. We use a global circulation model to simulate the HDO cycle in the atmosphere. Our model is an upgrade of the previous model presented in Montmessin et al. (2005, Journal of Geophysical Research, 110(E3), E10004. doi:10.1029/2004JE002357). We then simulate the effect of the global dust storm that affected Mars during the summer of 2018, and show that it should have had a strong impact on the vertical distribution of HDO, allowing it to reach higher altitudes. Such simulations are intended to be compared with observations from the Trace Gas Orbiter, currently in orbit around Mars. Key Points: We reimplemented the HDO cycle in a more recent version of the Laboratoire de Météorologie Dynamique Mars global climate modelWe reproduce the observed gradient of the deuterium to hydrogen ratio between cold and warm regionsThe global dust storm of Martian year 34 has a strong effect on the vertical distribution of HDO [ABSTRACT FROM AUTHOR]