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CO2-to-HCOOH Electrochemical Conversion on Nanostructured CuxPd100-x/Carbon Catalysts.
- Source :
- ChemElectroChem; 4/1/2021, Vol. 8 Issue 7, p1362-1368, 7p
- Publication Year :
- 2021
-
Abstract
- Selective electrochemical conversion of CO<subscript>2</subscript> to HCOOH is obtained at the surface of a carbon-supported bimetallic cathode material composed of copper and palladium nanoparticles. Polycrystalline copper or large copper particles are well-known to catalyze CO<subscript>2</subscript> reduction to hydrocarbons at relatively negative potentials, or when their surface is covered by copper oxides (Cu<subscript>2</subscript>O and CuO). Cu-based materials modified by various palladium contents (0< × <100), were synthesized by using the microwave-assisted polyol method to serve as a cathode in the selective CO<subscript>2</subscript>-into-HCOOH transformation. Herein, we developed a targeted preparation route toward the metal content/catalytic activity relationship correlating atomic ratio with faradaic efficiency (FE) to formate formation (ca. 60% FE) at - 0.72 V vs. RHE, which represents a 703 mV overpotential at pH=7. Consequently, the occurrence of this reduction reaction slows down the parallel H<subscript>2</subscript> production from the solvent consumption, while the neighboring Cu- Pd provides excellent activity and a good efficiency toward CO<subscript>2</subscript> reduction via the hydridation of the CO<subscript>2</subscript> molecule to orientate the reaction to formate rather than carbon monoxide or H2 evolution. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21960216
- Volume :
- 8
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- ChemElectroChem
- Publication Type :
- Academic Journal
- Accession number :
- 150161072
- Full Text :
- https://doi.org/10.1002/celc.202100268