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Trimethylsilyl Pseudohalide Adducts of GaCl3 and B(C6F5)3.
- Source :
- European Journal of Inorganic Chemistry; 5/26/2021, Vol. 2021 Issue 20, p1913-1920, 8p
- Publication Year :
- 2021
-
Abstract
- Me3Si−X (X=CN, N3, OCN, and SCN) was treated with the Lewis acids GaCl3 and B(C6F5)3 in toluene yielding the desired adducts Me3Si−X→GaCl3 and Me3Si−X→B(C6F5)3. All synthesized adducts were isolated and completely characterized including single crystal structure elucidations. The different structures, thermodynamics of formation and charge transfer effects are discussed on the basis of experimental and theoretical data. [ABSTRACT FROM AUTHOR]
- Subjects :
- LEWIS acids
CHARGE transfer
CRYSTAL structure
SINGLE crystals
THERMODYNAMICS
Subjects
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2021
- Issue :
- 20
- Database :
- Complementary Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 150671101
- Full Text :
- https://doi.org/10.1002/ejic.202100237