Back to Search
Start Over
Synthesis of Arylpalladium(II) Boronates: Confirming the Structure and Chemical Competence of Pre‐transmetalation Intermediates in the Suzuki–Miyaura Reaction.
- Source :
- Angewandte Chemie International Edition; 6/25/2021, Vol. 60 Issue 27, p14897-14901, 5p
- Publication Year :
- 2021
-
Abstract
- Palladium(II) boronates are recognized as fundamental pre‐transmetalation intermediates in Suzuki–Miyaura cross‐couplings. While these typically transient species have been detected and studied spectroscopically, it is conspicuous that they have never been isolated since this important reaction was discovered over forty years ago. This study reports the synthesis of a family of unprecedented arylpalladium(II) boronates that are, by design, kinetically stable at ambient temperature, both in solution and in the solid state. These properties enabled unambiguous crystallographic confirmation of their structure for the first time and their chemical competence in a Suzuki–Miyaura reaction was demonstrated. [ABSTRACT FROM AUTHOR]
- Subjects :
- SUZUKI reaction
CHEMICAL structure
SOLID solutions
PERFORMANCE
PALLADIUM
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 60
- Issue :
- 27
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 151003088
- Full Text :
- https://doi.org/10.1002/anie.202104802