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Kinetic resolution of N-aryl β-amino alcohols via asymmetric aminations of anilines.
- Source :
- Chemical Communications; 9/21/2021, Vol. 57 Issue 74, p9394-9397, 4p
- Publication Year :
- 2021
-
Abstract
- An efficient kinetic resolution of N-aryl β-amino alcohols has been developed via asymmetric para-aminations of anilines with azodicarboxylates enabled by chiral phosphoric acid catalysis. Broad substrate scope and high kinetic resolution performances were afforded with this method. Control experiments supported the critical roles of the NH and OH group in these reactions. [ABSTRACT FROM AUTHOR]
- Subjects :
- KINETIC resolution
AMINATION
ANILINE
AMINO alcohols
ALCOHOL
PHOSPHORIC acid
CATALYSIS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 74
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 152489201
- Full Text :
- https://doi.org/10.1039/d1cc03117a