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Tandem Functionalization‐Carboxylation Reactions of π‐Systems with CO2.
- Source :
- Chinese Journal of Chemistry; Nov2021, Vol. 39 Issue 11, p3116-3126, 11p
- Publication Year :
- 2021
-
Abstract
- The tandem catalytic functionalization/carboxylation of double as well as triple carbon‐carbon bonds with CO2 represent an emerging research area in synthetic organic methodology. In particular, the combination of mild reaction conditions, stoichiometric acceptor/donorless conditions (visible light photoredox catalysis) and chiral catalysts contributed to a rapid development of this intriguing research area capable of creating chemical diversity/ complexity from readily available unsaturated hydrocarbons and CO2 as a C1‐buinding block. The most recent developments in the field have been collected in the present review article and organized, based on the different sets of π‐systems/intermediates/reactive partners employed (i.e., nickelalactones, organo‐halides) as well as synthetic strategies (i.e., visible‐light photo redox catalysis). [ABSTRACT FROM AUTHOR]
- Subjects :
- CARBOXYLATION
CARBON-carbon bonds
VISIBLE spectra
CARBON dioxide
CATALYSIS
CATALYSTS
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 39
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153050709
- Full Text :
- https://doi.org/10.1002/cjoc.202100450