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Ensembles from silver clusters and cucurbit[6]uril-containing linkers.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 11/14/2021, Vol. 50 Issue 42, p15267-15273, 7p
- Publication Year :
- 2021
-
Abstract
- In this work, organic supramolecular linkers involving cucubit[6]urils CB[6] and N,N′-hexamethylene-bis(pyrazinyl hexafluorophosphate) (BPHF@CB[6]) were utilized to assemble dodenuclear silver chalcogenolate clusters into three one-dimensional (1D) materials under different synthesis conditions. These three crystal structures of CB[6]-based sliver cluster-organic rotaxane frameworks were well resolved, and their emission properties were investigated systematically. This construction strategy involving organic supramolecular linkers gives a new methodology for cluster-assembled materials with intriguing structural and functional properties. [ABSTRACT FROM AUTHOR]
- Subjects :
- SILVER clusters
CUCURBITACEAE
CRYSTAL structure
CONSTRUCTION materials
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 50
- Issue :
- 42
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153440877
- Full Text :
- https://doi.org/10.1039/d1dt02505h