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Temperature‐Controlled Divergent Synthesis of Tetrasubstituted Alkenes and Pyrrolo[1,2‐a]indole Derivatives via Iridium Catalysis.
- Source :
- Asian Journal of Organic Chemistry; Dec2021, Vol. 10 Issue 12, p3308-3320, 13p
- Publication Year :
- 2021
-
Abstract
- We have achieved an Ir(III)‐catalyzed temperature‐controlled divergent synthesis of tetrasubstituted alkenes and pyrrolo[1,2‐a]indole derivatives through C−H alkenylation/DG migration and [3+2] annulation, respectively. This method has various advantageous features: a) excellent regio‐ and stereoselectivity and good functional group tolerance, b) broad substrate scope and moderate to excellent yields, c) mild redox‐neutral reaction conditions and operational simplicity. [ABSTRACT FROM AUTHOR]
- Subjects :
- INDOLE derivatives
IRIDIUM
ALKENES
CATALYSIS
ALKENYLATION
INDOLE
Subjects
Details
- Language :
- English
- ISSN :
- 21935807
- Volume :
- 10
- Issue :
- 12
- Database :
- Complementary Index
- Journal :
- Asian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 154104180
- Full Text :
- https://doi.org/10.1002/ajoc.202100476