Back to Search
Start Over
M6PS5X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 12/28/2021, Vol. 50 Issue 48, p17901-17905, 5p
- Publication Year :
- 2021
-
Abstract
- A series of M<subscript>6</subscript>PS<subscript>5</subscript>X (M = Ag, Cu; X = Cl, Br) nonlinear optical (NLO) chalcohalides with special MS<subscript>3</subscript>X ligands have been synthesized in this work. Their critical optical performances were systematically measured and the research results show that all of them exhibit strong NLO responses (2.0–2.7 × commercial AgGaS<subscript>2</subscript>) and high laser-damage thresholds (1.7–2.3 × AgGaS<subscript>2</subscript>), indicating their potential application as good NLO candidates. Furthermore, first-principles calculations were used to study their inherent structure–property relationships and chalcohalides can be expected to be optimal systems for the exploration of new promising IR NLO crystals. [ABSTRACT FROM AUTHOR]
- Subjects :
- LASER damage
LIGANDS (Chemistry)
NONLINEAR optics
CRYSTALS
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 50
- Issue :
- 48
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 154122663
- Full Text :
- https://doi.org/10.1039/d1dt03251h