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High proton conduction in an excellent water-stable gadolinium metal–organic framework.

Authors :
Xing, Xiu-Shuang
Fu, Zhi-Hua
Zhang, Ning-Ning
Yu, Xiao-Qing
Wang, Ming-Sheng
Guo, Guo-Cong
Source :
Chemical Communications; 1/28/2019, Vol. 55 Issue 9, p1241-1244, 4p
Publication Year :
2019

Abstract

A new metal–organic framework with excellent water stability, {H[(N(CH<subscript>3</subscript>)<subscript>4</subscript>)<subscript>2</subscript>][Gd<subscript>3</subscript>(NIPA)<subscript>6</subscript>]}·3H<subscript>2</subscript>O (1, H<subscript>2</subscript>NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10<superscript>−2</superscript> S cm<superscript>−1</superscript> (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
55
Issue :
9
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
154431997
Full Text :
https://doi.org/10.1039/c8cc08700h