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Strong emission at 1000 nm from Pr3+/Yb3+-codoped multicomponent tellurite glass.

Authors :
Burtan-Gwizdala, Bozena
Reben, Manuela
Cisowski, Jan
Yousef, El Sayed
Lisiecki, Radoslaw
Nosidlak, Natalia
Source :
Pure & Applied Chemistry; Feb2022, Vol. 94 Issue 2, p147-156, 10p
Publication Year :
2022

Abstract

To increase the emission intensity of Pr SP 3+ sp ions, Yb SP 3+ sp ions appear as an efficient sensitizer [[13]]. Due to a non-exponential character of the decay data, we have determined the experimental lifetime as being equal to the effective lifetime defined as HT <math overflow="scroll" xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>t</mi><mtext>eff</mtext></msub><mo>=</mo><mo> </mo><mi>t</mi><mo>-</mo><mi>I</mi><mo>(</mo><mi>t</mi><mo>)</mo><mo>-</mo><mi>d</mi><mi>t</mi><mo>/</mo><mo> </mo><mi>I</mi><mo>(</mo><mi>t</mi><mo>)</mo><mo>-</mo><mi>d</mi><mi>t</mi></math> ht Graph (4) Graph: Fig. [[36]]) HT <math overflow="scroll" xmlns="http://www.w3.org/1998/Math/MathML"><mi> </mi><mo>=</mo><mn>1</mn><mo>-</mo><mfrac><msub><mi> </mi><mtext>Pr</mtext><mo>-</mo><mtext>Yb</mtext></msub><msub><mi> </mi><mtext>Pr</mtext></msub></mfrac></math> ht Graph (5)where I i SB Pr-Yb sb and I i SB Pr sb are the effective lifetimes with and without Yb SP 3+ sp -coping, respectively, but for the same concentration of Pr SP 3+ sp ions. Emission spectra Emission spectra of Ln-doped samples TPr and TPrYb were measured in the same conditions allowing one to compare their relative intensities; additionally, in order to demonstrate the effect of the Pr SP 3+ sp ion concentration ( I N i SB Pr sb ; see Table 1) on the emission spectra, the PL signal of both samples (in arbitrary units) has been divided by I N i SB Pr sb . [Extracted from the article]

Details

Language :
English
ISSN :
00334545
Volume :
94
Issue :
2
Database :
Complementary Index
Journal :
Pure & Applied Chemistry
Publication Type :
Academic Journal
Accession number :
155665324
Full Text :
https://doi.org/10.1515/pac-2021-0701