Back to Search
Start Over
Morphology-Controlled Electrocatalytic Performance of Two-Dimensional VSe2 Nanoflakes for Hydrogen Evolution Reactions.
- Source :
- ACS Applied Nano Materials; 2/25/2022, Vol. 5 Issue 2, p2087-2093, 7p
- Publication Year :
- 2022
-
Abstract
- VSe<subscript>2</subscript> is a typical two-dimensional (2D) transition-metal dichalcogenide material with various physical properties, such as ultrahigh electrical conductivity, controversial magnetism, and active catalytic properties. However, controllable preparation of VSe<subscript>2</subscript> 2D structures poses many challenges, and their application has not yet been developed. Here, we controllably synthesize VSe<subscript>2</subscript> 2D flakes on highly oriented pyrolytic graphite (HOPG) using molecular beam epitaxy. By controlling the growth temperature and the evaporation rate of the source, we obtained various morphologies of VSe<subscript>2</subscript> flakes, including single- and multilayers with triangular and belt shapes. Compared with the triangular structures of the flakes, the one-dimensional nanobelt structures have a larger edge density and can provide more catalytic active sites. Hydrogen evolution reaction results indicate that the belt-shaped VSe<subscript>2</subscript> flakes exhibit superior catalytic performance. Due to the presence of plenty of edges, the overpotential of the belt-shaped VSe<subscript>2</subscript> is 543 mV at a current density of 1 mA/cm<superscript>2</superscript>, which is much lower than that in the triangular flakes. The VSe<subscript>2</subscript> flakes with a larger edge density are more conductive than the regular triangular flakes after loading metal atoms due to the efficient dispersion of the metal atoms. As a result, the multistructure of Co particle-decorated VSe<subscript>2</subscript> flakes achieves a high catalytic performance with 352 mV overpotential at a current density of 10 mA/cm<superscript>2</superscript>, demonstrating their potential applications in the catalyst field. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 25740970
- Volume :
- 5
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- ACS Applied Nano Materials
- Publication Type :
- Academic Journal
- Accession number :
- 155959764
- Full Text :
- https://doi.org/10.1021/acsanm.1c03812