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Self-Condensation of Acetone of Strontium Stannate under Supercritical Conditions.

Authors :
Veshchitsky, G. A.
Smirnov, A. V.
Mashchenko, N. V.
Koklin, A. E.
Bogdan, V. I.
Source :
Russian Journal of Physical Chemistry B: Focus on Physics; Dec2021, Vol. 15 Issue 8, p1299-1302, 4p
Publication Year :
2021

Abstract

Aldol condensation of acetone on strontium stannate is studied at a temperature of 250–400°C and a pressure of 2.5 and 12.5 MPa. The main reaction products are mesityl oxide and isophorone. It is shown that the SrSnO<subscript>3</subscript> catalyst is stable under supercritical conditions and its productivity with respect to mesityl oxide isomers at 350°C and 12.5 MPa equals 9 g h<superscript>–1</superscript> , which is higher than in the gas phase. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
19907931
Volume :
15
Issue :
8
Database :
Complementary Index
Journal :
Russian Journal of Physical Chemistry B: Focus on Physics
Publication Type :
Academic Journal
Accession number :
156375868
Full Text :
https://doi.org/10.1134/S1990793121080133