One-Step Solvothermal Synthesis of Ni Nanoparticle Catalysts Embedded in ZrO2 Porous Spheres to Suppress Carbon Deposition in Low-Temperature Dry Reforming of Methane.

Ni nanoparticle catalysts embedded in ZrO₂ porous spheres and ZrO₂ porous composite spheres, SiO₂-ZrO₂, MgO-ZrO₂, and Y₂O₃-ZrO₂, with 83−115 nm diameter and 167–269 m²/g specific surface area were prepared by a one-pot and one-step solvothermal reaction from precursor solutions consisting of Ni(NO₃)₂‧6H₂O, Zr(OⁿBu)₄, and acetylacetone in moist ethanol combined with either Si(OEt)₄, magnesium acetylacetate, or Y(OⁱPr)₃. The obtained Ni catalysts have high specific surface areas of 130–196 m²/g, even after high-temperature reduction by H₂ at 450 °C for 2 h. They were utilized as catalysts for low-temperature dry reforming of methane (DRM) at 550 °C to suppress carbon deposition on Ni nanoparticles. The Ni catalysts embedded in SiO₂-ZrO₂ and Y₂O₃-ZrO₂ demonstrated high catalytic activity and long stability in the reaction. Moreover, carbon deposition on Ni nanoparticles in the DRM reaction was effectively suppressed in when using the SiO₂-ZrO₂ and Y₂O₃-ZrO₂ composites. [ABSTRACT FROM AUTHOR]