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Visible‐Light Assisted Covalent Surface Functionalization of Reduced Graphene Oxide Nanosheets with Arylazo Sulfones.
- Source :
- Chemistry - A European Journal; 5/6/2022, Vol. 28 Issue 26, p1-6, 6p
- Publication Year :
- 2022
-
Abstract
- We present an environmentally benign methodology for the covalent functionalization (arylation) of reduced graphene oxide (rGO) nanosheets with arylazo sulfones. A variety of tagged aryl units were conveniently accommodated at the rGO surface via visible‐light irradiation of suspensions of carbon nanostructured materials in aqueous media. Mild reaction conditions, absence of photosensitizers, functional group tolerance and high atomic fractions (XPS analysis) represent some of the salient features characterizing the present methodology. Control experiments for the mechanistic elucidation (Raman analysis) and chemical nanomanipulation of the tagged rGO surfaces are also reported. [ABSTRACT FROM AUTHOR]
- Subjects :
- NANOSTRUCTURED materials
FUNCTIONAL groups
ARYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 28
- Issue :
- 26
- Database :
- Complementary Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 156737587
- Full Text :
- https://doi.org/10.1002/chem.202200333