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Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones.
- Source :
- Chemical Communications; 5/28/2022, Vol. 58 Issue 43, p6308-6311, 4p
- Publication Year :
- 2022
-
Abstract
- A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61–99% yields in the presence of a PN<superscript>H</superscript>P-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated. [ABSTRACT FROM AUTHOR]
- Subjects :
- FORMATES
HYDROSILYLATION
RUTHENIUM catalysts
KETONES
SILYL ethers
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 43
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 157125758
- Full Text :
- https://doi.org/10.1039/d2cc00666a