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A comparative study of the nonlinear rheological properties of three different cellulose nanofibril suspensions.
- Source :
- Physics of Fluids; May2022, Vol. 34 Issue 5, p1-17, 17p
- Publication Year :
- 2022
-
Abstract
- This study focused on the nonlinear rheological characterization of three types of cellulose nanofibril (CNF) suspensions under large amplitude oscillatory shear (LAOS) flow. Three different CNFs were produced, two by mechanical fibrillation alone under different conditions [here named microfibrillated cellulose (MFC) and U-CNF] and the other by mechanical fibrillation after carboxymethylation (CM-CNF). MFC and U-CNF had broad width distributions, whereas CM-CNF had narrower fibril width and width distribution due to the presence of charged carboxymethyl groups. Nonlinear stress responses of the prepared suspensions were analyzed using the sequence of physical processes method. All CNF suspensions exhibited intracycle rheological transitions composed of three physical processes: (1) structure recovery, (2) elastic deformation to early stage yielding, and (3) late-stage yielding. MFC and U-CNF suspensions exhibited similar rheological transitions overall. However, CM-CNF suspension had a higher network recovery rate within a shorter time and showed an additional yielding step due to the complex interplay between recovery and yielding dynamics. This result originated from complete nanofibrillation and charged functional groups on fibril surfaces. Rapid reformation of effective fibril–fibril contacts in CM-CNF suspension was attributed to electrostatic repulsions and complete nanosized lateral dimensions. In addition, excitation frequency was found to influence intracycle rheological transitions. A range of intracycle rheological transitions became narrower on increasing frequency because the time period for each transition was not enough under faster flow conditions. In particular, the characteristic yielding step of CM-CNF suspension disappeared on increasing frequency, which suggested that high-frequency excitation might be unfavorable for the nonlinear viscoelastic characterization of soft materials under LAOS flow. [ABSTRACT FROM AUTHOR]
- Subjects :
- RHEOLOGY
CELLULOSE
ELASTIC deformation
COMPARATIVE studies
CARBOXYMETHYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 10706631
- Volume :
- 34
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Physics of Fluids
- Publication Type :
- Academic Journal
- Accession number :
- 157217259
- Full Text :
- https://doi.org/10.1063/5.0089656