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Asymmetric Radical Cyclization of Alkenes by Stereospecific Homolytic Substitution of Sulfinamides.
- Source :
- Angewandte Chemie; 7/18/2022, Vol. 134 Issue 29, p1-5, 5p
- Publication Year :
- 2022
-
Abstract
- We report a novel asymmetric radical cyclization of alkenes via stereospecific homolytic substitution of sulfinamides. This reaction produces a variety of cyclic sulfinamides with excellent stereocontrol. The protocol features broad functional group tolerance, high product diversity, and easy accessibility to feedstocks, and outlines a new pathway for the synthesis of chiral cyclic sulfinamides. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 134
- Issue :
- 29
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 157908118
- Full Text :
- https://doi.org/10.1002/ange.202201027