Improved Modeling of Mars' HDO Cycle Using a Mars' Global Climate Model.

HDO and the D/H ratio are essential to understand Mars past and present climate, in particular with regard to the evolution through ages of the Martian water cycle. We present here new modeling developments of the HDO cycle with the Laboratoire de Météorologie Dynamique Mars Global Climate Model (GCM). The present study aims at exploring the behavior of the D/H ratio cycle and its sensitivity to the modeling of water ice clouds and the formulation of the fractionation by condensation. Our GCM simulations are compared with observations provided by the Atmospheric Chemistry Suite (ACS) on board the ESA/Roscosmos Trace Gas Orbiter (TGO), and reveal that the model quite well reproduces the temperature and water vapor fields, which offers a good basis for representing the D/H ratio cycle. The comparison also emphasizes the importance of modeling the state of supersaturation, resulting from the microphysical processes of water ice clouds, to correctly account for the water vapor and the D/H ratio of the middle‐to‐upper atmosphere. This work comes jointly with a detailed comparison of the measured D/H profiles by TGO/ACS and the model outputs, conducted in the companion paper of Rossi et al. (2022, https://doi.org/10.1029/2022JE007201) (this issue). Plain Language Summary: The D/H ratio observed in a planetary atmosphere is traditionally used as a proxy to estimate the initial water reservoir of the planet. We present here an improved global circulation model including HDO, the main isotope of water on Mars. The updated model takes into account the details of the formation of clouds and their radiative effect. It also includes the effect of photochemistry on HDO and deuterated species. We find that supersaturation is key to the representation of the D/H cycle by making the hygropause more porous, allowing more HDO in the upper atmosphere. It also reduces the efficiency of the isotopic fractionation occurring at condensation. We present here comparisons between observations by the Atmospheric Chemistry Suite spectrometer onboard the orbiter TGO. While the model is globally in agreement with the observations, the inability of the model to reproduce the observed vertical distribution of dust, especially during the Global Dust Storm, causes discrepancies in the representation of water vapor. The model reveals the importance of representing the state of supersaturation to correctly account for the water vapor amount reaching the top of the atmosphere and estimate the D/H ratio at escape. Key Points: The HDO cycle has been implemented in the last version of the Laboratoire de Météorologie Dynamique Mars Global Climate Model including microphysics and radiative effect of water ice cloudsKinetics effect is now included in HDO fractionation during condensation and proves to be significantSupersaturation, the presence of which is regulated by cloud processes, alters significantly the relative abundances of HDO and H2O [ABSTRACT FROM AUTHOR]