Study of the dielectric breakdown strength of CO2–O2 mixtures by considering ion kinetics in a spatial–temporal growth avalanche model.

The gas mixture CO₂–O₂ has been considered as an insulation and arc-quenching medium in gas-insulated switchgears. In this paper, the dielectric breakdown properties of CO₂–O₂ mixtures at different O₂ concentrations and gas pressures were studied theoretically by considering ion kinetics in a spatial–temporal growth avalanche model. A kinetic scheme that includes all the main reactions likely to occur in CO₂–O₂ mixtures is presented. An improved method to calculate the dielectric strength of the gas mixture is developed, based on an avalanche model that considers both spatial growth and temporal processes. Next, the reaction rates of ionization, attachment, detachment and ion conversion, the effective ionization Townsend coefficient α_eff/N, and reduced critical electric field strength (E/N)_cr in CO₂–O₂ mixtures at different mixing ratios and gas pressures are analyzed in detail. Finally, a pulsed Townsend experiment is performed to verify the validity and accuracy of the calculation method. Based on this, one detachment reaction rate is modified to yield more accurate results. Better consistency between the results and the experimental values supports the validity of the kinetic system, reaction rates, and the improved calculation method. [ABSTRACT FROM AUTHOR]