Effect of hydrostatic pressure on the structural, elastic, and optoelectronic properties of vacancy-ordered double perovskite Cs2PdBr6.

The vacancy-ordered double perovskite Cs₂PdBr₆ has the advantages of good optoelectronic properties, environmental friendliness, and high stability. It has been experimentally confirmed by researchers as an optoelectronic material with broad application prospects and research value, and is regarded as a potential substitute for lead halide perovskites. In this paper, based on the first-principles calculations in the framework of density functional theory, the crystal structure, elastic, electronic, and optical properties of Cs₂PdBr₆ under hydrostatic pressure of 0–6 GPa have been investigated with a step size of 0.5 GPa. The calculated results obtained under the condition of 0 GPa hydrostatic pressure are in good agreement with the existing experimental values. When the hydrostatic pressure is applied, the crystal structure parameters of Cs₂PdBr₆ appear nonlinear changes, but it can still maintain a stable cubic crystal structure. With the increase of pressure, the bulk modulus, shear modulus, and Young's modulus of Cs₂PdBr₆ increase gradually, and its ductility also improves gradually. Hydrostatic pressure can reduce the bandgap value of Cs₂PdBr₆, thereby enhancing the optoelectronic properties such as absorption and conductivity. In summary, hydrostatic pressure can change the bandgap value of Cs₂PdBr₆, improve its optoelectronic performance, and make it more suitable for use as the light-absorbing layer in solar cells. [ABSTRACT FROM AUTHOR]