A dually responsive cyanostilbene derivative for paper fluorescence anti-counterfeiting and informational encryption.

Stimuli-responsive fluorescent materials are ideal materials for paper anti-counterfeiting applications. However, the single responsiveness and the lacking of dynamics present the risk of being deciphered. Herein, we designed a series of cyanostilbene derivatives (ACNs) with fluorescence responses to acid or base. ACN1 with pyridine and hydroxyl groups exhibit dually responsive fluorescence "ON" in the solid state due to the ionization-enhanced intramolecular charge transfer (ICT) effect. Other ACNs with either pyridine or hydroxyl unit show only single responsiveness. Fluorescence papers (FPs) prepared by a simple dipping into the solutions of ACNs maintain the responsive fluorescence performance. FP1H with high ACN1 content exhibits time-dependent dynamic fluorescent colour changes by hydrogen chloride (HCl) vapour fumigation. The applications of paper anti-counterfeiting and information encryption are developed by combining ACN1 with other single-responsive ACNs. Moreover, a four-dimensional (4D) code with time-dependent information changes is designed. Our work provides new materials for the field of paper fluorescent anti-counterfeiting encryption. [ABSTRACT FROM AUTHOR]