Front Cover: Stereospecific Access to α‐ and β‐N‐Glycosylamine Derivatives by a Metal Free O‐to‐N [3,3]‐Sigmatropic Rearrangement (Eur. J. Org. Chem. 41/2022).

Allegorically, the Old Bridge reflecting on the water surface represents the two faces of the sugar derivative on which the rearrangement may take place: from top (the Old Bridge) or bottom (the mirrored Old Bridge). B The Front Cover b exhibits a photo of the famous Ponte Vecchio (Old Bridge) on the Arno River, as a tribute to the city of Florence and its University, where all the research has been carried out. Front Cover: Stereospecific Access to - and -N-Glycosylamine Derivatives by a Metal Free O-to-N [3,3]-Sigmatropic Rearrangement (Eur. J. Org. [Extracted from the article]