Long-term validation of MIPAS ESA operational products using MIPAS-B measurements.

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) was a limb-viewing infrared Fourier transform spectrometer that operated from 2002 to 2012 aboard the Environmental Satellite (ENVISAT). The final re-processing of the full MIPAS mission Level 2 data was performed with the ESA operational version 8 (v8) processor. This MIPAS dataset includes not only the retrieval results of pressure–temperature and the standard species H 2 O, O 3 , HNO 3 , CH 4 , N 2 O, and NO 2 but also vertical profiles of volume mixing ratios of the more difficult-to-retrieve molecules N 2 O 5 , ClONO 2 , CFC-11, CFC-12 (included since v6 processing), HCFC-22, CCl 4 , CF 4 , COF 2 , and HCN (included since v7 processing). Finally, vertical profiles of the species C 2 H 2 , C 2 H 6 , COCl 2 , OCS, CH 3 Cl, and HDO were additionally retrieved by the v8 processor. The balloon-borne limb-emission sounder MIPAS-B was a precursor of the MIPAS satellite instrument. Several flights with MIPAS-B were carried out during the 10-year operational phase of ENVISAT at different latitudes and seasons, including both operational periods when MIPAS measured with full spectral resolution (FR mode) and with optimised spectral resolution (OR mode). All MIPAS operational products (except HDO) were compared to results inferred from dedicated validation limb sequences of MIPAS-B. To enhance the statistics of vertical profile comparisons, a trajectory match method has been applied to search for MIPAS coincidences along the 2 d forward and backward trajectories running from the MIPAS-B measurement geolocations. This study gives an overview of the validation results based on the ESA operational v8 data comprising the MIPAS FR and OR observation periods. This includes an assessment of the data agreement of both sensors, taking into account the combined errors of the instruments. The differences between the retrieved temperature profiles of both MIPAS instruments generally stays within ±2 K in the stratosphere. For most gases – namely H 2 O, O 3 , HNO 3 , CH 4 , N 2 O, NO 2 , N 2 O 5 , ClONO 2 , CFC-11, CFC-12, HCFC-22, CCl 4 , CF 4 , COF 2 , and HCN – we find a 5 %–20 % level of agreement for the retrieved vertical profiles of both MIPAS instruments in the lower stratosphere. For the species C 2 H 2 , C 2 H 6 , COCl 2 , OCS, and CH 3 Cl, however, larger differences (within 20 %–50 %) appear in this altitude range. [ABSTRACT FROM AUTHOR]