Pseudohexagonal Nb2O5‐Decorated Carbon Nanotubes as a High‐Performance Composite Anode for Sodium Ion Batteries.

To promote the commercial application of sodium ion batteries (SIBs), new high‐stability and high‐capacity anode materials are needed. Metal oxides show great promise, but significant issues relating to their low electrical conductivity and unstable structure during charge storage must be resolved. Herein, a new composite anode consisting of pseudohexagonal Nb2O5 (TT‐Nb2O5) nanoparticles strongly anchored to carbon nanotubes (CNT) through a glucose‐derived carbon framework (Nb2O5/g‐CNT) was synthesised and assessed for use as the anode in SIBs. This represents the first application of TT‐Nb2O5 in SIBs. The composite is shown to offer high specific capacity (203 mAh g−1 at 0.2 A g−1), good rate capability (53 mAh g−1 at high current density of 5 A g−1), and a high‐capacity retention rate (135 mAh g−1 at 0.2 A g−1 between 25 and 300 cycles). This is attributed to high electrical conductivity and flexibility offered by the designed carbon framework, the superior capacity of the TT‐Nb2O5 and the linkage between the two provided by the bonding glucose derived carbon. This work therefore demonstrates a scalable route for the application of metal oxides in future high‐performance SIB systems. [ABSTRACT FROM AUTHOR]