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In Situ Synthesis of Cu3P/P‐Doped g‐C3N4 Tight 2D/2D Heterojunction Boosting Photocatalytic H2 Evolution†.
- Source :
- Chinese Journal of Chemistry; Jan2023, Vol. 41 Issue 2, p173-180, 8p
- Publication Year :
- 2023
-
Abstract
- Comprehensive Summary: Heterojunction design in a two‐dimensional (2D) fashion has been deemed beneficial for improving the photocatalytic activity of g‐C3N4 because of the promoted interfacial charge transfer, yet still facing challenges. Herein, we construct a novel 2D/2D Cu3P nanosheet/P‐doped g‐C3N4 (PCN) nanosheet heterojunction photocatalyst (PCN/Cu3P) through a simple in‐situ phosphorization treatment of 2D/2D CuS/g‐C3N4 composite for photocatalytic H2 evolution. We demonstrate that the 2D lamellar structure of both CuS and g‐C3N4 could be well reserved in the phosphorization process, while CuS and g‐C3N4 in‐situ transformed into Cu3P and PCN, respectively, leading to the formation of PCN/Cu3P tight 2D/2D heterojunction. Owing to the large contact area provided by intimate face‐to‐face 2D/2D structure, the PCN/Cu3P photocatalyst exhibits significantly enhanced charge separation efficiency, thus achieving a boosted visible‐light‐driven photocatalytic behavior. The highest rate for H2 evolution reaches 5.12 μmol·h–1, nearly 24 times and 368 times higher than that of pristine PCN and g‐C3N4, respectively. This work represents an excellent example in elaborately constructing g‐C3N4‐based 2D/2D heterostructure and could be extended to other photocatalyst/co‐catalyst system. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 41
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 160813207
- Full Text :
- https://doi.org/10.1002/cjoc.202200445