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Electrosynthetic C−O Bond Activation in Alcohols and Alcohol Derivatives.
- Source :
- Angewandte Chemie International Edition; 1/23/2023, Vol. 62 Issue 4, p1-28, 28p
- Publication Year :
- 2023
-
Abstract
- Alcohols and their derivatives are ubiquitous and versatile motifs in organic synthesis. Deoxygenative transformations of these compounds are often challenging due to the thermodynamic penalty associated with the cleavage of the C−O bond. However, electrochemically driven redox events have been shown to facilitate the C−O bond cleavage in alcohols and their derivatives either through direct electron transfer or through the use of electron transfer mediators and electroactive catalysts. Herein, a comprehensive overview of preparative electrochemically mediated protocols for C−O bond activation and functionalization is detailed, including direct and indirect electrosynthetic methods, as well as photoelectrochemical strategies. [ABSTRACT FROM AUTHOR]
- Subjects :
- SCISSION (Chemistry)
CHARGE exchange
ORGANIC synthesis
ALCOHOL
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 62
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 161338718
- Full Text :
- https://doi.org/10.1002/anie.202211952